Rust lets you "reach lower" down the stack than Go does, as well as using less memory. There are prominent Node people in both languages; for example, tj moved to Go long ago, and Node shops like npm are deploying Rust today.
Finally, it's easier to extend Node with Rust than Go, since Rust has no runtime. https://www.neon-bindings.com/ is a great example of this, and we're working with the Webpack team so that you'll be able to just drop Rust code into your project and have Webpack do its thing, producing webassembly that your Node can use.
Finally, it doesn't have to be an either-or: Dropbox is using both Rust and Go where appropriate.