Being a full stack microsoft developer, I've always tended to lean towards those technologies, mostly due to work and what I've been accustomed to. While I know and am proficient in .NET, I absolutely hate it. Too cumbersome and bloated for my liking, thankfully I don't do much in these days (I'm primarily doing classic asp nowadays and love it. Anything you can do in PHP I can do in ASP, better :) ).
I have been looking at Python lately, as everything I've read about makes me think it would be a good transition from a procedural language like ASP. If I ever get some free time, I plan on checking it out :)